Hydrogenation during ligand exchange reactions between ferrocene and pyrene
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چکیده
منابع مشابه
Retention of the Cluster Core Structure during Ligand Exchange Reactions of Carboxylato-Substituted Metal Oxo Clusters
The exchange of the carboxylato ligands of Zr4O2(methacrylato)12 in reactions with carboxylic acids proceeds with retention of the composition and structure of the cluster core. This was concluded from exchange/re-exchange experiments and from comparison of the IR bands of the cluster core of the original and ligand-exchanged clusters. The IR bands were assigned on the basis of DFT calculations...
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Rr-CooA is a CO-sensor heme protein, where binding of CO with the heme group stimulates a transcriptional activator activity of CooA. In this process, the heme undergoes a series of ligand exchanges. In the ferric form, the heme has Cys75 and Pro2 as the axial ligands. In the reduced ferrous form, the heme has His77 instead of Cys75 as an axial ligand with Pro2. Only in the reduced form, CooA c...
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A comparison between the reactivity behavior of two lutetium benzyl complexes supported by different ferrocene-diamide ligands towards aromatic N-heterocycles, such as 1-methylimidazole, isoquinoline, and pyridines, is presented. The two ferrocene-diamide ancillary ligands differ in their nitrogen-donor substituent: adamantyl for one and t-butyldimethylsilyl for the other. The synthesis and cha...
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1979
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v79-153